Scenes from the JRM Lab

Scenes from the JRM Lab

Scenes from the JRM Lab

Scenes from the JRM Lab

Scenes from the JRM Lab

     

Ultrafast Molecular Photoswitch

An international collaboration led by researchers from the Kansas State University Physics Department and the Oxford University Chemistry Department has studied ultrafast processes in the molecular photoswitch quadricyclane, published recently in Nature Chemistry.


Quadricyclane and norbornadiene are two isomers, that is molecules with the same chemical formula but different geometry, which interconvert upon absorption of ultraviolet light. Quadricyclane is the higher-energy isomer and can be used to store solar energy, which is then released by a catalytic process as heat. So-called molecular solar thermal (MOST) devices exploit such isomer pairs to, for instance, warm houses by absorbing energy from the sun during the day and then releasing it at night.

The experiment, led by Kansas State Physics professor Daniel Rolles and his graduate student Kurtis Borne, used ultrashort light pulses produced by the FERMI free-electron laser facility in Trieste, Italy, to track the conversion between the two isomers on a timescale of femtoseconds. The experimental results were interpreted with the help of state-of-the-art computer simulations done in Oxford. The combined study discovered faster than previously identified pathways leading to the conversion, which may help designing new ways of controlling the outcome and efficiency of this important class of photoreactions.

See also our press release via the K-State Physics Department.

     

Recently Published Papers:

  • Generation of fast photoelectrons in strong-field emission from metal nanoparticles
    Erfan Saydanzad, Jeffrey Powell, Tim Renner, Adam Summers, Daniel Rolles, Carlos Trallero-Herrero, Matthias F. Kling, Artem Rudenko, Uwe Thumm
    Nanophotonics 14, 1355 (2025)
  • Hearing carrier-envelope offset frequency and phase in air with a microphone
    Meng Han, Ming-Chang Chen, Ming-Shian Tsai, Hao Liang
    Optica 12, 459 (2025)
Find more of our Publications...
     

This Week at JRM

Week of 11 May 2025

  Final Exams
Mon1:30 pm Nuts & Bolts
News & status (Hybrid, CW119)
Tue 
Wed 
Thu3:00 pm PhD Award Party
For our latest grads (CW119)
Fri 

See full calendar...

     
     

What's New?

Daniel Rolles, professor in atomic, molecular, and optical physics, has been selected as a 2024 Fellow of the American Physical Society for pioneering experiments on imaging ultrafast molecular reactions with XUV and X-ray free-electron lasers, and for advancing our understanding of the interaction of ultra-intense X-ray pulses with atoms and molecules.

Read more news...